A radial continuum phase transition with algebraic decayResearch Paper
Motivation: continuum phase transitions with a power-law tail
Whether identical classical particles in , interacting only through a stable radial pair potential, can undergo a phase transition is a classical existence problem of rigorous statistical mechanics, highlighted in Simon's list of problems in mathematical physics (Simon 1984). A transition shows up as a singularity of the thermodynamic free energy. Earlier rigorous continuum transitions rely on extra structure — two species, many-body terms, hard cores, or interactions defined through a fixed partition into boxes — or on a mean-field limit in which the potential itself changes. A natural requirement for a satisfactory answer is a single fixed pair potential with a bounded core and an explicit integrable power-law tail.
Timeline
- 1965 — Motzkin and Straus's weighted-graph maximization, later used for occupation bounds (Motzkin–Straus 1965).
- 1966 — Lebowitz and Penrose: rigorous van der Waals–Maxwell theory in the Kac limit (Lebowitz–Penrose 1966).
- 1970 — Ruelle's superstability framework (Ruelle 1970).
- 1971 — Ruelle: transition for a symmetric two-species continuum system (Ruelle 1971).
- 1973 — Gerardi, Marchioro, Olivieri and Presutti extend the Lebowitz–Penrose limit to superstable references (GMOP 1973).
- 1984 — Simon lists the problem among fifteen problems in mathematical physics.
- 1998–1999 — Lebowitz, Mazel and Presutti: liquid–vapor transition with attractive pair and repulsive four-body interactions (PRL 1998, J. Stat. Phys. 1999).
- 2026 — He, Jauslin, Lebowitz and Peled: transition for a finite-range box-modified Kac pair interaction (CMP 2026); Dereudre and Renaud-Chan: density coexistence for saturated many-body interactions (arXiv:2602.11078).
- 2026 — Two OpenAI preprints (OpenAI Math Release, September 24, 2026): a radial potential with divergent core and tail with a temperature singularity, and the present A radial continuum phase transition with algebraic decay, which claims a bounded continuous potential with . Neither is peer reviewed, and the theorem is not formally verified.
Setting
Particles live in ; a radial pair potential is a function (in Lean, ℝ≥0 → ℝ) applied to pair distances. For the cube and ,
The potential is stable if for all configurations. The canonical free energy at density is
The packing constant is , where is the largest number of points in at mutual distance ; in Lean IsPackingDensity p asserts this limit. StrictTemperatureCorner f βc asserts finite left and right derivatives at with the right one strictly smaller, and non-differentiability.
Formalization targets
Milestone: the corner at the central density
At the single density : there are a bounded continuous stable with for and such that exists for all and
Goal: a common corner on a density interval
There are a bounded continuous , constants with
an open interval and one such that for every the free energy exists and is finite for every , and
This is Theorem 1.1 of the source. Both statements are published on the platform with status Open.
Significance
The result itself. The theorem gives a single-species, bounded, continuous radial pair potential with an explicit integrable power-law tail whose canonical free energy has a strict temperature corner at one critical inverse temperature for a whole interval of densities. The interaction is a genuine radial function of separations with all long-range terms kept; boxes appear only in the estimates. It does not treat Lennard–Jones-type potentials and does not identify the phases as conventional fluids. The companion preprint has a divergent core but only an tail; the fixed power margin here needs a quantitative range estimate not present there.
Formalizing it. The statement fixes the model completely (free boundary conditions on , Lebesgue measure without temperature normalization, , particles), so a formal proof would settle exactly which version of the problem is solved. The infrastructure (thermodynamic limits, convex duality for pressures, Kac comparisons) is reusable for the companion mission.
Difficulty
The Lebowitz–Penrose theory produces non-convex mean-field free energies only in the limit where the attraction range tends to infinity, and that limiting object is not the free energy of any fixed potential. A single potential must therefore contain infinitely many attractions at growing ranges, and the required singularity must survive all of them. Density coexistence at fixed temperature does not by itself give a temperature corner at a fixed density: two supporting slopes with equal density coordinate and different energy coordinates are needed. A pointwise power bound constrains how strong the successive attractions may be relative to their ranges, which is why a quantitative comparison with an explicit error is required.
Formalization scope
- Positions are
EuclideanSpace ℝ (Fin 3); distances enter throughnndist, so the potential is a function onℝ≥0. Boundedness, continuity, stability with , and decay with are separate conjuncts. - is existentially quantified but pinned by
IsPackingDensity p(a limit), and is required;packingNumberis asSupover a bounded set of naturals. IsCanonicalFreeEnergy φ ρ fasserts for every , so is determined on ; one-sided derivatives useHasDerivWithinAtonIic βcandIci βc.- The goal requires the interval to lie in and to be independent of .
- Needed infrastructure: superstability and occupation moments, existence of thermodynamic limits and their convex duality, a Motzkin–Straus bound, quantitative Kac comparison, and subdifferential persistence arguments.
Selected references
- B. Simon, Fifteen problems in mathematical physics, in Perspectives in Mathematics, Birkhäuser, 1984, 423–454. https://math.caltech.edu/SimonPapers/R27.pdf
- T. S. Motzkin and E. G. Straus, Maxima for graphs and a new proof of a theorem of Turán, Canad. J. Math. 17 (1965), 533–540. https://doi.org/10.4153/CJM-1965-053-6
- J. L. Lebowitz and O. Penrose, Rigorous treatment of the van der Waals–Maxwell theory of the liquid-vapor transition, J. Math. Phys. 7 (1966), 98–113. https://doi.org/10.1063/1.1704821
- D. Ruelle, Superstable interactions in classical statistical mechanics, Comm. Math. Phys. 18 (1970), 127–159. https://doi.org/10.1007/BF01646091
- D. Ruelle, Existence of a phase transition in a continuous classical system, Phys. Rev. Lett. 27 (1971), 1040–1041. https://doi.org/10.1103/PhysRevLett.27.1040
- A. Gerardi, C. Marchioro, E. Olivieri and E. Presutti, Van der Waals–Maxwell theory, Lebowitz–Penrose limit and superstable interactions, Comm. Math. Phys. 29 (1973), 219–231. https://doi.org/10.1007/BF01645248
- J. L. Lebowitz, A. E. Mazel and E. Presutti, Liquid–vapor phase transitions for systems with finite-range interactions, J. Stat. Phys. 94 (1999), 955–1025. https://doi.org/10.1023/A:1004591218510
- Q. He, I. Jauslin, J. Lebowitz and R. Peled, Liquid-vapor transition in a model of a continuum particle system with finite-range modified Kac pair potential, Comm. Math. Phys. 407 (2026), 240. https://doi.org/10.1007/s00220-026-05735-w
- D. Dereudre and C. Renaud-Chan, First-order phase transition for Gibbs point processes with saturated interactions, arXiv:2602.11078 (2026). https://arxiv.org/abs/2602.11078v1
- R. T. Rockafellar and R. J.-B. Wets, Variational Analysis, Springer, 1998. https://doi.org/10.1007/978-3-642-02431-3
- OpenAI, A continuum temperature singularity for a radial pair potential, OpenAI Math Release preprint, September 24, 2026. https://github.com/openai/math/blob/adc7f1241b42e322a6451854ab7e4b4c146bf78a/preprints/A-continuum-temperature-singularity-for-a-radial-pair-potential-September-24-2026/paper.pdf
- OpenAI, A radial continuum phase transition with algebraic decay, OpenAI Math Release preprint, September 24, 2026 (Theorem 1.1, p. 1). https://github.com/openai/math/blob/adc7f1241b42e322a6451854ab7e4b4c146bf78a/preprints/A-radial-continuum-phase-transition-with-algebraic-decay-September-24-2026/paper.pdf