A continuum temperature singularity for a radial pair potentialResearch Paper
Motivation: phase transitions for continuum particles
Whether a single species of classical particles in , interacting only through a stable radial pair potential, can undergo a phase transition is one of the long-standing existence questions of rigorous statistical mechanics; it appears in Simon's list of problems in mathematical physics (Simon 1984). A phase transition is detected as a loss of regularity of the thermodynamic free energy. Lattice models and continuum models with extra structure (several species, many-body terms, hard cores, box-restricted interactions) were handled long ago; ordinary pair potentials finite at every positive separation remained the difficult case.
Timeline
- 1966 — Lebowitz and Penrose give the rigorous van der Waals–Maxwell theory in the Kac (long-range) limit (Lebowitz–Penrose 1966).
- 1970 — Ruelle's superstability framework for classical continuum systems (Ruelle 1970).
- 1971 — Ruelle proves a transition for the two-species Widom–Rowlinson model (Ruelle 1971).
- 1975 — Israel's convex construction gives coexistence for hard-core continuum particles with a spherically symmetric pair perturbation (Israel 1975).
- 1984 — Simon lists the continuum phase-transition problem among fifteen problems in mathematical physics.
- 1998–1999 — Lebowitz, Mazel and Presutti prove a liquid–vapor transition for attractive pair plus repulsive four-body interactions (PRL 1998, J. Stat. Phys. 1999).
- 2025–2026 — He, Jauslin, Lebowitz and Peled: coexistence for a box-modified Kac pair interaction (CMP 2026); Dereudre and Renaud-Chan: low-temperature coexistence for saturated (many-body) interactions (arXiv:2602.11078).
- 2026 — An OpenAI preprint, A continuum temperature singularity for a radial pair potential (OpenAI Math Release, September 24, 2026), claims an admissible radial pair potential in whose canonical free energy has a temperature corner at one critical inverse temperature for every density in an open interval. It has not been peer reviewed and the theorem is not formally verified.
Setting
A radial pair potential is on with . It is admissible if is Borel measurable, is finite and locally bounded on , and
- as ;
- on some interval with ;
- for some ;
- (stability) for all and all configurations.
With and free boundary conditions, the canonical partition function is
and the canonical free-energy density at density is
In Lean, radialPotential φ takes values in EReal (value ⊤ at the origin), energy is the pair sum, partition φ β L N is the integral above, and HasCanonicalFreeEnergy φ f says for all .
Formalization targets
Goal: a strict temperature corner throughout a density interval
There exist an admissible with as , a free-energy function realizing the canonical limit for every , a nonempty open interval and one such that for every the one-sided -derivatives exist and
This is Theorem 1.1 of the source (MainStatement). The goal is published on the platform with status Open.
Significance
The result itself. The theorem exhibits a genuine one-species pair potential, finite at every positive separation and with all cross-cube interactions retained, whose canonical free energy is not in temperature at a fixed density, with one critical temperature for an entire interval of densities. It does not concern the Lennard–Jones potential, does not identify the coexisting states as liquid/vapor/solid, and does not give a power-law tail ; formulations of the historical problem that require such a margin are not resolved by it. A companion preprint (A radial continuum phase transition with algebraic decay) gives a bounded potential with tail .
Formalizing it. The statement is fully explicit about the model, normalization, and boundary conditions, so a formal proof would remove any ambiguity about which version of the problem is solved. It requires thermodynamic limits for superstable continuum systems, convex-analytic facts about pressures, and a Kac/Lebowitz–Penrose comparison with uniform estimates, none of which is currently in Mathlib.
Difficulty
Density coexistence for a grand-canonical system does not by itself produce a temperature corner at a fixed density; one needs two supporting slopes of the pressure with the same density coordinate and different energy coordinates. Classical tools for transitions (Peierls arguments, reflection positivity, Kac limits) either need lattice structure, many-body terms, or a limit in which the potential itself changes. Here a single fixed potential must be built through infinitely many attractions at growing ranges, and the convex supporting-slope information must survive every approximation step while preserving stability and integrable tails.
Formalization scope
- Space is
EuclideanSpace ℝ (Fin 3); the potential isEReal-valued with⊤at the origin, and the Boltzmann weight is when the energy is⊤. Stability is stated inEReal, which also rules out⊥. - Free boundary conditions on the closed cube , Lebesgue measure without temperature normalization, , and via
Nat.floor; the limit is over real . - One-sided derivatives are
HasDerivWithinAtonIic βcandIci βc, so both are finite real numbers; is pinned byHasCanonicalFreeEnergyfor every , so it cannot be chosen freely near . - is open, order-connected, nonempty and contained in ; is independent of .
- Needed infrastructure: superstability estimates, existence of canonical and grand-canonical thermodynamic limits, Legendre duality for pressures, the Lebowitz–Penrose limit. These are reusable for the companion mission.
Selected references
- B. Simon, Fifteen problems in mathematical physics, in Perspectives in Mathematics, Birkhäuser, 1984, 423–454. https://math.caltech.edu/SimonPapers/R27.pdf
- J. L. Lebowitz and O. Penrose, Rigorous treatment of the van der Waals–Maxwell theory of the liquid-vapor transition, J. Math. Phys. 7 (1966), 98–113. https://doi.org/10.1063/1.1704821
- D. Ruelle, Superstable interactions in classical statistical mechanics, Comm. Math. Phys. 18 (1970), 127–159. https://doi.org/10.1007/BF01646091
- D. Ruelle, Existence of a phase transition in a continuous classical system, Phys. Rev. Lett. 27 (1971), 1040–1041. https://doi.org/10.1103/PhysRevLett.27.1040
- R. B. Israel, Existence of phase transitions for long-range interactions, Comm. Math. Phys. 43 (1975), 59–68. https://doi.org/10.1007/BF01609141
- J. L. Lebowitz, A. E. Mazel and E. Presutti, Liquid–vapor phase transitions for systems with finite-range interactions, J. Stat. Phys. 94 (1999), 955–1025. https://doi.org/10.1023/A:1004591218510
- Q. He, I. Jauslin, J. Lebowitz and R. Peled, Liquid–vapor transition in a model of a continuum particle system with finite-range modified Kac pair potential, Comm. Math. Phys. 407 (2026), 240. https://doi.org/10.1007/s00220-026-05735-w
- D. Dereudre and C. Renaud-Chan, First-order phase transition for Gibbs point processes with saturated interactions, arXiv:2602.11078 (2026). https://arxiv.org/abs/2602.11078v1
- OpenAI, A radial continuum phase transition with algebraic decay, OpenAI Math Release preprint, September 24, 2026. https://github.com/openai/math/blob/adc7f1241b42e322a6451854ab7e4b4c146bf78a/preprints/A-radial-continuum-phase-transition-with-algebraic-decay-September-24-2026/paper.pdf
- OpenAI, A continuum temperature singularity for a radial pair potential, OpenAI Math Release preprint, September 24, 2026 (Theorem 1.1, p. 2). https://github.com/openai/math/blob/adc7f1241b42e322a6451854ab7e4b4c146bf78a/preprints/A-continuum-temperature-singularity-for-a-radial-pair-potential-September-24-2026/paper.pdf